| Startnr. | Land | Interpret | Lied Musik (M) und Text (T) |
| Erste Hälfte | |||
| 1–9 | Estland | Uku Suviste | What Love Is M/T: Uku Suviste, Sharon Vaughn |
| Griechenland | Stefania Στεφανία | SUPERG!RL M: Dimitris Kontopoulos, Arcade; T: Dimitris Kontopoulos, Arcade, Sharon Vaughn |
|
| Island | Daði og Gagnamagnið | Think About Things M/T: Daði Freyr |
|
| Moldau | Natalia Gordienko | Prison M/T: Dimitris Kontopoulos, Phillip Kirkorow, Sharon Vaughn |
|
| Österreich | Vincent Bueno | Alive M: Vincent Bueno, David „Davey“ Yang, Felix van Göns, Artur Aigner; T: Vincent Bueno |
|
| Polen | Alicja Szemplińska | Empires M/T: Patryk Kumór, Dominic Buczkowski-Wojtaszek, Laurell Barker, Frazer Mac |
|
| San Marino | Senhit | 9. März 2020 | |
| Serbien | Hurricane | Hasta la vista M: Nemanja Antonić; T: Kosana Stojić, Sanja Vučić |
|
| Tschechien | Benny Cristo | Kemama M: Osama Verse-Atile; T: Ben Cristovao, Charles Sarpong |
|
| Zweite Hälfte | |||
| 10–18 | Albanien | Arilena Ara | Shaj M: Darko Dimitrov, Lazar Cvetkovski; T: Lindon Berisha |
| Armenien | Athena Manoukian Աթենա Մանուկեան | Chains On You M: Athena Manoukian, DJ Paco; T: Athena Manoukian |
|
| Bulgarien | VICTORIA Виктория | Tears Getting Sober M/T: VICTORIA, Borislaw Milanow, Lukas Oscar, Cornelia Wiebols |
|
| Dänemark | Ben & Tan | Yes M/T: Emil Adler Lei, Jimmy Jansson, Linnea Deb |
|
| Finnland | Aksel Kankaanranta | Looking Back M/T: Joonas Angeria, Connor McDonough |
|
| Georgien | Tornike Kipiani თორნიკე ყიფიანი | Take Me As I Am M/T: Tornike Kipiani |
|
| Lettland | Samanta Tīna | Still Breathing M: Samanta Tīna; T: Aminata Savadogo |
|
| Portugal | Elisa | Medo de Sentir M/T: Marta Carvalho |
|
| Schweiz | Gjon’s Tears | Répondez-moi M/T: Gjon Muharremaj, Xavier Michel, Alizé Oswald, Jeroen Swinnen |
